姓 名 ： 謝光勇
職 稱(chēng) ： 教授
單 位 ：中南民族大學(xué)化學(xué)與材料科學(xué)學(xué)院
學(xué)科專(zhuān)業(yè) ：高分子化學(xué)
研究方向：烯烴可控聚合，金屬有機(jī)化學(xué)，芳烴氨氧化催化劑
學(xué)者簡(jiǎn)介：謝光勇，博士，教授，博士生導(dǎo)師。中國(guó)化學(xué)會(huì)會(huì)員，國(guó)家民委中青年英才人選，湖北省新世紀(jì)高層次人才工程人選，武漢市青年科技晨光計(jì)劃人選，湖北省化學(xué)化工學(xué)會(huì)橡塑專(zhuān)業(yè)委員會(huì)委員，國(guó)家自然科學(xué)基金委通訊評(píng)審專(zhuān)家，湖北省科技廳和武漢市科技局會(huì)評(píng)專(zhuān)家。1994年本科畢業(yè)于武漢大學(xué)化學(xué)系；2002年獲武漢大學(xué)化學(xué)與分子科學(xué)學(xué)院高分子化學(xué)與物理專(zhuān)業(yè)博士學(xué)位；2002至2005年在中科院上海有機(jī)化學(xué)研究所金屬有機(jī)化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室作博士后， 2005年至今在中南民族大學(xué)化學(xué)與材料學(xué)院工作。在國(guó)內(nèi)外刊物上發(fā)表論文一百余篇，其中六十余篇論文被SCI收錄；已授權(quán)發(fā)明專(zhuān)利三十余項(xiàng)；獲省部級(jí)科技獎(jiǎng)兩項(xiàng)；主持包括兩項(xiàng)國(guó)家自然科學(xué)基金在內(nèi)的國(guó)家、省部級(jí)項(xiàng)目和橫向課題等二十余項(xiàng)。
主持的主要科研項(xiàng)目：
1. 國(guó)家自然科學(xué)基金（批準(zhǔn)號(hào)：21172269），新型非茂類(lèi)同核和異核雙金屬烯烴聚合催化劑的合成和性能研究，2012－2015
2. 國(guó)家自然科學(xué)基金（批準(zhǔn)號(hào)：20302011），含鹵素取代基的新型非茂過(guò)渡金屬烯烴聚合催化劑的合成及應(yīng)用研究，2004－2006
3. 國(guó)家自然科學(xué)基金重點(diǎn)項(xiàng)目子課題（批準(zhǔn)號(hào)：40830852），全新世南海珊瑚礁白化的頻率與恢復(fù)周期，2009－2012
4. 中國(guó)博士后科學(xué)基金（批準(zhǔn)號(hào)：2003033343），金屬有機(jī)絡(luò)合物的合成及其催化烯烴聚合研究，2003－2005
5. 2003年度上海市博士后基金，含鹵素取代基的新型烯烴聚合催化劑的研究，2003－2005
6. 國(guó)家民委科研項(xiàng)目（批準(zhǔn)號(hào)：05ZN05），新型烯烴可控聚合催化劑的合成及應(yīng)用研究，2006－2008
7. 武漢市青年科技晨光計(jì)劃（批準(zhǔn)號(hào)：200750731301），新型非茂類(lèi)烯烴聚合催化劑的合成及結(jié)構(gòu)可控烯烴聚合研究，2007－2009
8. 湖北省自然科學(xué)基金（批準(zhǔn)號(hào)：2008CDZ038），新型鐵系乙烯齊聚催化劑及乙烯可控齊聚與共聚的研究，2009－2010
9. 武漢市應(yīng)用基礎(chǔ)研究計(jì)劃（2014010101010017），新型非茂類(lèi)雙核烯烴聚合催化劑的合成及其催化性能研究，2014－2015
10. 橫向項(xiàng)目（批準(zhǔn)號(hào)：HZY14023），氯代甲苯氨氧化催化劑的研究開(kāi)發(fā)，2014-2015
11. 中央高?；究蒲袠I(yè)務(wù)費(fèi)（批準(zhǔn)號(hào)：CZP17040），甲基芳烴氨氧化的高活性長(zhǎng)壽命催化劑的研制與工業(yè)化應(yīng)用，2017－2019
12. 橫向項(xiàng)目：（批準(zhǔn)號(hào)：HZY21043），對(duì)氯甲苯氨氧化催化劑的研究開(kāi)發(fā)，2021
13. 中南民族大學(xué)省部級(jí)科研機(jī)構(gòu)重大招標(biāo)課題（PTZD22007），高活性長(zhǎng)壽命的氯代甲苯氨氧化催化劑的研發(fā)及產(chǎn)業(yè)化，2022
14. 成果轉(zhuǎn)化：發(fā)明專(zhuān)利“制備2,5-二氯苯腈的方法和專(zhuān)用催化劑及其制備方法” （專(zhuān)利號(hào)：ZL201711329592.1）轉(zhuǎn)讓給武漢綠本科技有限公司，2022
15. 成果轉(zhuǎn)化：發(fā)明專(zhuān)利“非茂類(lèi)雙齒雙釩配合物及制備方法與用途”（專(zhuān)利號(hào)：ZL201711338878.6）轉(zhuǎn)讓給武漢綠本科技有限公司，2022
16. 橫向項(xiàng)目：（批準(zhǔn)號(hào)：HZY23041），對(duì)氯甲苯氨氧化催化劑開(kāi)發(fā)與工業(yè)化生產(chǎn)，2023
主要獎(jiǎng)項(xiàng):
1、謝光勇等，武漢市自然科學(xué)優(yōu)秀學(xué)術(shù)論文獎(jiǎng)三等獎(jiǎng)，2010-LW-01-081。
2、謝光勇等，取代甲苯氨氧化的含釩復(fù)合氧化物催化劑的研發(fā)與應(yīng)用，湖北省技術(shù)發(fā)明獎(jiǎng)二等獎(jiǎng)，2016F-035-2-008-003-R1。
3、謝光勇等，甲基芳烴氨氧化的高活性長(zhǎng)壽命催化劑的研制與工業(yè)化應(yīng)用，中國(guó)石油和化學(xué)工業(yè)聯(lián)合會(huì)技術(shù)發(fā)明獎(jiǎng)三等獎(jiǎng)，2017FMR0030-3-1。
教研項(xiàng)目及教學(xué)成果獎(jiǎng)：
1、材料化學(xué)專(zhuān)業(yè)基礎(chǔ)與應(yīng)用并重的人才培養(yǎng)體系的建設(shè)與實(shí)踐，湖北省高校省級(jí)教學(xué)研究項(xiàng)目，2011（主持）
2、張愛(ài)清、李琳、張道洪、謝光勇、劉書(shū)正、張俊珩. 材料化學(xué)戰(zhàn)略性新興產(chǎn)業(yè)人才培養(yǎng)模式探索與實(shí)踐. 中南民族大學(xué)教學(xué)成果獎(jiǎng)一等獎(jiǎng)，2016。
3、張愛(ài)清、李琳、張道洪、謝光勇、劉書(shū)正、張俊珩. 民族院校材料化學(xué)專(zhuān)業(yè)“三階遞進(jìn)”式人才培養(yǎng)模式實(shí)踐. 湖北省高等學(xué)校教學(xué)成果一等獎(jiǎng)（證書(shū)編號(hào)：2018105），2018。
主要授權(quán)專(zhuān)利：
1. 謝光勇，鄭穹，黃馳. 用于氨氧化法制備大茴香腈的催化劑及其制法和用途. 專(zhuān)利號(hào) ZL01106634.2 2003.6.25
2. 謝光勇，錢(qián)長(zhǎng)濤，姜衛(wèi)華. 含鹵素取代基的β-酮亞胺類(lèi)前過(guò)渡金屬鈦配合物、合成方法和用途. 專(zhuān)利號(hào) ZL200510028047.X, 2008.4.30.
3. 謝光勇，錢(qián)長(zhǎng)濤，姜衛(wèi)華. 乙烯聚合催化劑、合成方法和用途. 專(zhuān)利號(hào) ZL200510028280.8, 2008.1.16
4. 謝光勇, 張東方, 艾海濤, 雷祿. 含鹵素的不對(duì)稱(chēng)吡啶雙亞胺類(lèi)鐵和鈷配合物、制備方法及用途. 專(zhuān)利號(hào)ZL200810174720.4, 2011.8.31.
5. 謝光勇, 艾海濤, 張愛(ài)清. 一種制備線(xiàn)性低密度聚乙烯的方法及雙功能催化劑體系. 專(zhuān)利號(hào)ZL201010515021.9, 2012.11.14.
6. 謝光勇, 張愛(ài)清, 李金林. 一種納米釩酸鉻及制備方法和應(yīng)用. 專(zhuān)利號(hào)ZL201210009878.2, 2013.10.23.
7. 謝光勇, 張愛(ài)清, 李金林. 一種納米磷酸氧釩及其制備方法和應(yīng)用. 專(zhuān)利號(hào)ZL201210009899.4, 2013.06.26.
8. 謝光勇, 張翔, 雷祿, 張愛(ài)清. 用于乙烯原位共聚制備支化聚乙烯的雙功能催化劑體系及應(yīng)用. 專(zhuān)利號(hào)ZL201210490377.0, 2015.4.1.
9. 謝光勇, 張愛(ài)清. 甘蔗渣/聚乙烯復(fù)合材料及其制備方法. 專(zhuān)利號(hào)ZL201310235043.3, 2015.08.26.
10. 謝光勇, 徐曉航，李龍, 劉公毅, 張愛(ài)清. β-酮亞胺配位的雙核銅配合物、制備方法及用途. 專(zhuān)利號(hào)ZL201310173979.8, 2016.04.06
11. 謝光勇, 李龍, 劉公毅, 張愛(ài)清, 熊焰. 非茂類(lèi)β-酮亞胺型三齒雙金屬鈦配合物、制備方法與應(yīng)用. 專(zhuān)利號(hào) ZL201410391325.7, 2017.6.20
12. 謝光勇, 劉公毅, 李龍, 張愛(ài)清, 熊焰. 非茂類(lèi)三齒雙核鈦配合物、制備方法及用途. 專(zhuān)利號(hào)ZL201410393654.5, 2017.6.16
13. 謝光勇, 肖驍,?羅德榮, 熊焰, 張愛(ài)清. 非茂類(lèi)雙齒雙釩配合物及制備方法與用途. 專(zhuān)利號(hào)ZL201711338878.6, 2020.6.12.
14. 謝光勇, 黃馳,?游向前,?黃業(yè)迎,?熊焰,?張愛(ài)清,?李金林. 制備2,5-二氯苯腈的方法和專(zhuān)用催化劑及其制備方法. 專(zhuān)利號(hào)ZL201711329592.1, 2021.9.24.
15. 謝光勇, 黃業(yè)迎,?張倩,?鄭浩,?熊焰,?陳川,?周新花. 氨氧化反應(yīng)制備間苯二腈的專(zhuān)用催化劑及制備方法與用途. 專(zhuān)利號(hào)ZL201811544906.4, 2022.2.18.
16. 謝光勇, 張倩,?黃業(yè)迎,?鄭浩,?熊焰,?周新花. 氨氧化法制備鄰氯苯腈的專(zhuān)用催化劑及制備方法與用途. 專(zhuān)利號(hào)ZL201811543455.2, 2022.2.22.
17. 謝光勇, 黃業(yè)迎,?張倩,?鄭浩,?熊焰,?張愛(ài)清,?李金林. 氨氧化法制備對(duì)氯苯腈的專(zhuān)用催化劑及制備方法與用途. 專(zhuān)利號(hào)ZL 201811543465.6, 2022.2.18.
18. 謝光勇, 李建, 熊焰. 氨氧化法制備對(duì)苯二甲腈的催化劑及制備方法與用途. 專(zhuān)利號(hào)ZL 201910243739.8, 2022.5.3.
19. 謝光勇, 董運(yùn)召, 熊焰,?周新花. 制備2,3,5,6-四氯苯甲腈的方法及專(zhuān)用催化劑和制備方法. 專(zhuān)利號(hào)ZL 202010323807.4, 2022.5.24.
20. 謝光勇, 鄭浩, 丁爽,?熊焰,?周新花. 氨氧化法制備2,4,6-三氯苯腈的方法和專(zhuān)用催化劑及制備方法. 專(zhuān)利號(hào)ZL 202010323817.8, 2022.9.27.
21. 謝光勇, 丁爽,?鄭浩, 董運(yùn)召, 熊焰. 氨氧化法制備2,6-二氯苯腈的專(zhuān)用催化劑及其制備方法和用途. 專(zhuān)利號(hào)ZL 202010323810.6, 2023.8.22.
22. 謝光勇, 鄭浩, 丁爽,?董運(yùn)召, 熊焰. 制備3,4-二氯苯甲腈的催化劑及制備方法和用途.專(zhuān)利號(hào)ZL 202010323822.9, 2023.10.13.
23. 謝光勇, 鄭浩, 唐萬(wàn)軍, 董運(yùn)召, 熊焰. 納米Cr2V4O13材料及其制備方法和應(yīng)用. 專(zhuān)利號(hào)ZL 202110464630.4, 2023.7.18.
近年來(lái)發(fā)表的部分論文：
1. Senlin Ren, Xiao Xiao, Pingzhou Huang, Ming Zhou, Tingcheng Li, Qingliang You, Guangyong Xie*. Synthesis, characterization and ethylene (co)polymerization of binuclear vanadium(IV) catalysts based on xanthene-bridged bis-salicylaldiminato ligands. European Polymer Journal, 2024, 202, 112660.
2. Jiahui Chen, Wanjun Tang*, Qingliang You, Biao Xiao, Guangyong Xie*. Improving the blue emission from Eu2+ by codoping Re3+ ions (Re=Y, La, Gd, Lu) in NaMgPO4. Optical Materials, 2024, 147, 114578.
3. Mengyuan Xue, Lu Lei, Senlin Ren, Tingcheng Li, Qingliang You, Guangyong Xie*. Significant cooperative effects in binuclear titanium complexes based on trifluoromethyl substituted bis-β-carbonylenamine ligands for ethylene (co)polymerization. Polymer, 2023, 277, 125995.
4. Mengyuan Xue, Yani Luo, Senlin Ren, Tingcheng Li, Qingliang You, Guangyong Xie*. Phenyl-bridged bis-salicylaldiminato binuclear titanium complexes for ethylene (co)polymerization. Journal of Polymer Research, 2023, 30(1), 28.
5. Chuanqing Du, Yeyin Huang, Wanjun Tang*, Lang Sun, Qingliang You, Tingcheng Li, Guangyong Xie*. Spray dried VCrO/SiO2 micro-spheroidal catalyst for the ammoxidation of p-chlorotoluene. Research on Chemical Intermediates, 2023, 49, 5361-5374.
6. Dongmei Zhao, Wanjun Tang*, Qingliang You, Tingcheng Li, Lang Sun, Guangyong Xie*. Catalytic performances of VPO/SBA-15 catalysts for ammoxidation of dichlorotoluenes. Research on Chemical Intermediates, 2023, 49, 4367-4382.
7. Yunyi Liu, Dongmei Zhao, Wanjun Tang*, Tingcheng Li, Qingliang You, Guangyong Xie*. Hydrothermal synthesis of monoclinic CrVO4 nanoparticles and catalytic ammoxidation of 2-chlorotoluene. Catalysis Letters, 2023, https://doi.org/10.1007/s10562-023-04305-2.
8. Wanjun Tang, Hao Zheng, Yunzhao Dong, Qingliang You, Tingcheng Li, Guangyong Xie*. Hollow flower-like Cr2V4O13 hierarchical micro-nano architectures: Controlled self-assembly synthesis and the outstanding catalytic performances for ammoxidation of chlorotoluenes. Molecular Catalysis, 2022, 518, 112062.
9. Wanjun Tang, Yunyi Liu, Shuang Ding, Dongmei Zhao, Tingcheng Li, Guangyong Xie*. Solvothermal synthesis of micro-cuboid MoV2O8 for vapor-phase ammoxidation of p-chlorotoluene. Research on Chemical Intermediates, 2022, 48, 4105-4118.
10. Guangyong Xie, Ming Wu, Wanjun Tang*, Tingcheng Li, Qingliang You, Biao Xiao. NUV-pumped red-emitting Ca9MnK(PO4)7 phosphor: energy transfer and charge compensation. Dalton Trans., 2022, 51, 11851-11858.
11. Yunzhao Dong, Tingcheng Li, Xiangqian You, Qingliang You, Lang Sun, Guangyong Xie*. A Novel Approach to Synthesize Dichlorobenzonitriles by Selective Ammoxidation. Research on Chemical Intermediates, 2022, 48, 1151-1158.
12. Yawen Qin, Tingcheng Li, Xiong Chen, Jian Li, Xiang Meng, Qingliang You, Guangyong Xie*. Asymmetric bis-salicylaldiminato binuclear titanium complexes for ethylene polymerization and copolymerization. New Journal of Chemistry, 2021, 45, 11390-11398.
13. Jian Li, Liwei Wang, Yawen Qin, Qingliang You, Tingcheng Li, Lang Sun, Xiangdan Li, Guangyong Xie*. Binuclear Titanium Complexes Coordinated by Rigid p-Phenylene Linked Bis-β-carbonylenamine: Synthesis, Structure, Ethylene Polymerization and Copolymerization with 1,5-Hexadiene. Appl. Organomet. Chem., 2020, 34, e5772.
14. Yani Luo, Jian Li, Derong Luo, Qingliang You, Zifeng Yang, Tingcheng Li, Xiangdan Li, Guangyong Xie*. Methylene-Bridged Tridentate Salicylaldiminato Binuclear Titanium Complexes as Copolymerization Catalysts for the Preparation of LLDPE through [Fe]/[Ti] Tandem Catalysis. Polymers, 2019, 11, 1114.
15. Yeying Huang, Tingcheng Li, Qingliang You, Xiangqian You, Qian Zhang, Daohong Zhang, Guangyong Xie*. Solvothermal synthesis and characterization of nanocrystalline vanadium-chromium composite oxides and catalytic ammoxidation of 2,6-dichlorotoluene. Chinese Journal of Catalysis, 2018, 39: 1814-1820.
16. Derong Luo, Yi Zeng, Xiong Chen, Ping Xia, Guangyong Xie*, Qingliang You, Li Zhang, Tingcheng Li, Xiangdan Li, Aiqing Zhang. Synthesis, Characterization and Olefin Polymerization Behaviors of Phenylene-bridged Bis-β- carbonylenamine Binuclear Titanium Complexes. RSC Advances, 2018, 8, 6954- 6964.
17. Li Zhang, Xiong Chen, Xiao Xiao, Derong Luo, Yi Zeng, Tingcheng Li, Xiangdan Li, Aiqing Zhang, Guangyong Xie*. A Novel Tridentate [ONS] Binuclear Titanium Complex Bearing Oxo-bridged Macrocyclic Structure for Ethylene Polymerization. Journal of Organometallic Chemistry, 2018, 856: 50-55.
18. Tingcheng Li, Zhi Lan, Guangyong Xie*, Derong Luo, Long Li, Shaofeng Xiong, Li Zhang, Lipeng Ouyang, Aiqing Zhang. Binuclear Titanium Catalysts Based on Methylene-bridged Tridentate Salicylaldiminato ligands for Ethylene Homo- and Copolymerization. Catalysis Letters, 2017, 147, 996-1005.
19. Liwei Wang, Xiangqian You, Qingliang You, Tingcheng Li, Aiqing Zhang, Guangyong Xie*. Synthesis and structures of mono(β-diiminato) copper complexes and their catalytic performances for homo- and copolymerizations of methylacrylate. Transition Metal Chemistry, 2016, 41(8), 857-866.
20. Tingcheng Li, Wen Song, Haitao Ai, Qingliang You, Aiqing Zhang, Guangyong Xie*. β-Diiminato Titanium Complexes with Varying Fluorine Substitution Patterns on the N-aryl Moiety: Probing the Effect of Ligand Substitution on Ethylene Polymerization. J. Polym. Res., 2015, 22, 631.
21. Guangyong Xie*, Xiang Zhang, Tingcheng Li, Long Li, Gongyi Liu, Aiqing Zhang*. Preparation of Linear Low-Density Polyethylene from Ethylene by Tandem Catalysis of Iron and Titanium Non-Metallocene Catalysts. Journal of Molecular Catalysis A: Chemical, 2014, 383-384: 121-127.
22. Guangyong Xie*, Gongyi Liu, Long Li, Tingcheng Li, Aiqing Zhang*, Jiwen Feng. Tandem Catalysis of Iron and Titanium Non-Metallocene Catalysts for the Production of Branched Polyethylene. Catalysis Communications, 2014, 45: 7-10.
23. Guangyong Xie*, Wen Song, Tingcheng Li, Xiaohang Xu, Zhi Lan, Yongsheng Li, Aiqing Zhang*. Synthesis, Characterization and Catalytic Behavior of Copper Complexes with Fluorosubstituted β-Ketoimine Ligands. J. Appl. Polym. Sci. 2014, 131(23), 41178.
24. Guangyong Xie*, Aiqing Zhang. An efficient selective synthesis of ethylbenzonitriles. Synth. Commun., 2012, 42(3): 375-379.
25. Yifu Zhang, Meijuan Fan, Xinghai Liu, Guangyong Xie*, Houbin Li, Chi Huang*. Synthesis of VO2(A) nanobelts by the transformation of VO2(B) under the hydrothermal treatment and its optical switching properties. Solid State Communications, 2012, 152: 253-256.
26. Yifu Zhang, Meijuan Fan, Min Zhou, Chi Huang, Chongxue Chen, Yuliang Cao, Guangyong Xie*, Houbin Li and Xinghai Liu. Controlled synthesis and electrochemical properties of vanadium oxides with different nanostructures. Bull. Mater. Sci., 2012, 35(3): 369-376.
27. Guangyong Xie*, Aiqing Zhang, Chi Huang. A novel synthesis of tolunitriles by selective ammoxidation. Research on Chemical Intermediates, 2010, 36(8): 969-973.
28. Hengquan Yang*, Zhancheng Ma, Yong Qing*, Guangyong Xie*, Jie Gao, Li Zhang, Jinhua Gao, Lin Du. A periodic mesoporous hybrid material with a built-in palladium complex: An efficient catalyst for the Suzuki coupling and alcohol oxidation. Applied Catalysis A: General, 2010, 382:312-321.
29. Guangyong Xie*, Tingcheng Li, Aiqing Zhang. Highly active and selective ethylene oligomerization catalysts: asymmetric 2,6-bis(imino)pyridyl iron (II) complexes with alkyl and halogen substitutients. Inorg. Chem. Commun., 2010, 13:1199-1202.
30. Guangyong Xie, Yuxue Li, Jie Sun, Changtao Qian*. Titanium Complexes with β-Ketoiminate Chelate Ligands for Ethylene Polymerization: the Significant Influence of Substituents on Structures and Catalytic Activities. Inorg. Chem. Commun., 2009, 12:796-799.
31. Guangyong Xie, Changtao Qian*. Dramatic Electronic Effect of Fluoro Substituents on the Olefin Polymerization Activity of mono β-Diiminato Titanium Complexes. J. Polym. Sci. A: Polym. Chem., 2008, 46(1): 211-217.
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